Some relays can be ordered with built-in internal diodes. I would check the relay to see if it indicates a diode on the diagram on the relay. Otherwise you'll want to verify with the part number. Same goes for valve coils.
However, modern microcontrollers such as PLUS1 generally do not require you to use valve coils or relays that have the diode. That's really only needed now when you're controlling the coil with a PLC or a mechanical switch.